Ichigo Kurosaki vs. Kenpachi Zaraki

Ichigo Kurosaki vs. Kenpachi Zaraki is Ichigo's third fight inside Seireitei during the Ryoka Invasion. As Ichigo is moving towards the Shrine of Penitence in order to rescue Rukia Kuchiki along with Ganju Shiba and Hanatarō Yamada, they are stopped in their tracks by a monstrous Reiatsu. Zaraki Kenpachi had been lying in wait for Ichigo having been told by Ikkaku Madarame his third seat that Ichigo was the strongest among the Ryoka. As Zaraki makes his presence known Ichigo feels a sword being thrust through him but realises that it was Kenpachi's blood lust. Ichigo realises that Ganju and Hanatarō do not stand a chance against him and therefore decides to stay back and fight him, entrusting the two to rescue Rukia. Thus after they leave Ichigo prepares to battle Zaraki Kenpachi.

Battle
When Zaraki sees Ichigo's battle stance, he compliments him on it although it still has openings, but admits that he likes his spiritual pressure. Zaraki acknowledges that he understands why Ikkaku lost to him, but makes note that Ichigo is still weaker than him, so he decides to give Ichigo a fighting stance. Zaraki then bares his chest and tells Ichigo to cut him anywhere and not to hold back. When Ichigo refuses to attack a unarmed opponent, while Zaraki commends him he states that it is simply a handicap and while he appreciates the thought Ichigo should save his sympathy for someone else. Zaraki warns him to either kill or be killed. Ichigo attacks Zaraki's exposed chest directly but causes no injury much to his confusion. Zaraki is unamused and disappointed and begins to unsheathe his Zanpakutō and tells Ichigo its his turn and asks him not to die to quickly.

When Ichigo's hand starts to bleed, Zaraki asks him why he seems to be surprised that his sword can't cut him. Zaraki then pushes Ichigo back using his arm against Ichigo's blade. Zaraki then explains why Ichigo's sword can't scratch him. He then takes out his own sword and asks Ichigo that at the very least he should try to place a dent upon his sword. Ichigo tries to run away from Zaraki but he can't seem to shake him and ends up running into at every turn. Zaraki eventually gets bored of chasing after him and sits down. He finally seems happy when Ichigo confronts him, Zaraki then asks if Ichigo is preparing to die or if he is surrendering. Ichigo refuses to do either, he goes to attack and finally succeeds in injuring Zaraki. Zaraki is extremely excited at the revelation that Ichigo can actually injure him, he tells Ichigo to not relax and keep his spiritual pressure up; he then attacks Ichigo.

The two clash and the battle continues with Zaraki having the upper hand but is happy to see Ichigo improving. He comments on how Ichigo is using the sounds of his bells to determine his position. Ichigo questions if Zaraki is underestimating him as he has not released his Zanpakutō. Zaraki then explains that his Zanpakutō has no name and has never had a seal on it; its currently in its true form. Ichigo is relieved to hear this and goes to attack once again but Zaraki goes to stop him and explains further about his Zanpakutō's state. He then stabs his Zanpakutō through Ichigo's breaking right through it and stabbing Ichigo in the chest; he then tells Ichigo that he warned him not to relax his spiritual pressure and that it has become weak because he saw a chance to win. He retracts out has sword frustrated that the battle was so easy and is now over. Ichigo eventually gets up much to Zaraki's surprise accompanied by a large burst of spiritual pressure. Ichigo then goes to attack Zaraki surprising him further and dealing him a serious injury to the left side from his shoulder down the side of his torso. Zaraki deflects Ichigo's next attack and stabs his sword into a nearby building, Zaraki begins to laugh and becomes extremely excited and says that now the fight is just getting started, noting that they should drag out the fight. He then lunges at Ichigo and causes his face to get cut by the blade just to get close to Ichigo. The battle escalates even more; regardless of his injuries, Zaraki continues to fight. It is then that Ichigo learns the drive behind Zaraki's personality.

Zaraki realizes that both he and Ichigo are evenly matched and he enjoys the feeling and euphoria of the moment, causing him to take off his eyepatch, making note that he considers Ichigo a worthy opponent so it only makes sense to fight him at full power. Zaraki's spiritual power rises as he removes his eyepatch, prompting Ichigo to wonder what is going on, so Zaraki explains to him what the eyepatch does. Zaraki then takes out his Zanpakutō and cuts a nearby building in half with one quick slash. He then tells Ichigo he will use all his power to kill him.

When Ichigo increases his power he greatly impresses Zaraki, it is then that Ichigo explains that he can do so by borrowing Zangetsu's power and fighting side by side with him, and that he will never lose to someone like him who only fights by himself. Zaraki asks if Zangetsu is Ichigo's Zanpakutō, fighting side by side with it, and borrowing its power, as Zaraki finds it ridiculous. He believes that Zanpakutō are just tools of war, believing that fighting side by side with one is the words for weak losers who are afraid to fight on their own. They both release their spiritual pressure and run at each other to make a final strike that release enough spiritual pressure that it collapses all the buildings around them. The battle ends in a draw, with Ichigo falling first and Kenpachi shortly after, both admitting defeat.

Aftermath
Yachiru calls for Retsu Unohana to heal Kenpachi, Kenpachi tells Yachiru that he lost but needs to pay him back. He raises his sword and acknowledges that he ignored it for a long time and wants it to communicate with him. Kenpachi does not hear it speak and faints, which scares Yachiru. This also marks the first time Ichigo has seriously fought a captain.