User blog comment:Godisme/Hear.Fear.Here/@comment-3256045-20120723151631/@comment-44061-20120723162645

That doesnt address the surprise and worried look of Urahara, also Hikifune has no prior relationship to Urahara he just happens to have filled her position as captain of the 12th division after she left. There is no proof of interaction between them other then general knowledge of one another. What does that minor link have to do with anything in this past chapter.